@diogo_bsantos Make sure you can connect the S3 bucket and AWS-related URL.
We had the same issue, PKIX, but it was not because of SSL. It was because of the proxy. We had to get an access to the URLs.
Switch your workbench to classic mode (easiest way) and console output to Debug, run the workflows, get the URLs, and ensure these URLs are open. If possible, work with your IT team; use wireshark to capture the traffic when you run the workflow and send it to your IT team.